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Phenol |
CAS 108-95-2 | ||
C6H5OH |
RTECS SJ3325000 | ||
Synonyms & Trade Names Carbolic acid, Hydroxybenzene, Monohydroxybenzene, Phenyl alcohol, Phenyl hydroxide |
DOT ID & Guide 1671 153 (solid) 2312 153 (molten) 2821 153 (solution) |
Exposure
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NIOSH REL: TWA 5 ppm (19 mg/m3) C 15.6 ppm (60 mg/m3) [15-minute] [skin] | ||
OSHA PEL: TWA 5 ppm (19 mg/m3) [skin] | |||
IDLH 250 ppm See: 108952 | Conversion 1 ppm = 3.85 mg/m3 |
Physical Description Colorless to light-pink, crystalline solid with a sweet, acrid odor. [Note: Phenol liquefies by mixing with about 8% water.] |
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MW: 94.1 |
BP: 359°F |
MLT: 109°F |
Sol(77°F): 9% |
VP: 0.4 mmHg |
IP: 8.50 eV |
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Sp.Gr: 1.06 |
Fl.P: 175°F |
UEL: 8.6% |
LEL: 1.8% |
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Combustible Solid | |||
Incompatibilities & Reactivities Strong oxidizers, calcium hypochlorite, aluminum chloride, acids |
Measurement Methods NIOSH 2546; OSHA 32 See: NMAM or OSHA Methods |
Personal Protection & Sanitation (See protection) Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: Daily Provide: Eyewash, Quick drench |
First Aid (See procedures) Eye: Irrigate immediately Skin: Soap wash immediately Breathing: Respiratory support Swallow: Medical attention immediately |
Important additional information about respirator selection Respirator Recommendations NIOSH/OSHA Up to 50 ppm: (APF = 10) Any air-purifying half-mask respirator with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100, P100. Click here for information on selection of N, R, or P filters. (APF = 10) Any supplied-air respirator Up to 125 ppm: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode (APF = 25) Any powered air-purifying respirator with an organic vapor cartridge in combination with a high-efficiency particulate filter. Up to 250 ppm: (APF = 50) Any air-purifying full-facepiece respirator equipped with organic vapor cartridge(s) in combination with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters. (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters. (APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate filter (APF = 50) Any self-contained breathing apparatus with a full facepiece (APF = 50) Any supplied-air respirator with a full facepiece Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode (APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus |
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Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact | |
Symptoms Irritation eyes, nose, throat; anorexia, weight loss; lassitude (weakness, exhaustion), muscle ache, pain; dark urine; cyanosis; liver, kidney damage; skin burns; dermatitis; ochronosis; tremor, convulsions, twitching | |
Target Organs
Eyes, skin, respiratory system, liver, kidneys |
See also: INTRODUCTION See ICSC CARD: 0070 See MEDICAL TESTS: 0182 |