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Picric acid |
CAS 88-89-1 | ||
(NO2)3C6H2OH |
RTECS TJ7875000 | ||
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Synonyms & Trade Names Phenol trinitrate; 2,4,6-Trinitrophenol [Note: An OSHA Class A Explosive (1910.109).] |
DOT ID & Guide 1344 113 (wet, > or =10% water) 3364 113 (wettted, > or =10% water) |
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Exposure
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NIOSH REL: TWA 0.1 mg/m3 ST 0.3 mg/m3 [skin] | ||
| OSHA PEL: TWA 0.1 mg/m3 [skin] | |||
| IDLH 75 mg/m3 See: 88891 | Conversion 1 ppm = 9.37 mg/m3 | ||
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Physical Description Yellow, odorless solid. [Note: Usually used as an aqueous solution.] |
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MW: 229.1 |
BP: Explodes above 572°F |
MLT: 252°F |
Sol: 1% |
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VP(383°F): 1 mmHg |
IP: ? |
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Sp.Gr: 1.76 |
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Fl.P: 302°F |
UEL: ? |
LEL: ? |
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| Combustible Solid | |||
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Incompatibilities & Reactivities Copper, lead, zinc & other metals; salts; plaster; concrete; ammonia [Note: Corrosive to metals. An explosive mixture results when the aqueous solution crystallizes.] |
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Measurement Methods NIOSH S228 (II-4) See: NMAM or OSHA Methods |
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Personal Protection & Sanitation (See protection) Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated/Daily Remove: When wet or contaminated Change: Daily |
First Aid (See procedures) Eye: Irrigate immediately Skin: Soap wash promptly Breathing: Respiratory support Swallow: Medical attention immediately |
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Important additional information about respirator selection Respirator Recommendations NIOSH/OSHA Up to 0.5 mg/m3: (APF = 5) Any quarter-mask respirator. Click here for information on selection of N, R, or P filters. Up to 1 mg/m3: (APF = 10) Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100, P100. Click here for information on selection of N, R, or P filters. (APF = 10) Any supplied-air respirator Up to 2.5 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode (APF = 25) Any powered air-purifying respirator with a high-efficiency particulate filter. Up to 5 mg/m3: (APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters. (APF = 50) Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode (APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter (APF = 50) Any self-contained breathing apparatus with a full facepiece (APF = 50) Any supplied-air respirator with a full facepiece Up to 75 mg/m3: (APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode (APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus Escape: (APF = 50) Any air-purifying, full-facepiece respirator with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus |
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| Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact | |
| Symptoms Irritation eyes, skin; sensitization dermatitis; yellow-stained hair, skin; lassitude (weakness, exhaustion), myalgia, anuria, polyuria; bitter taste, gastrointestinal disturbance; hepatitis, hematuria (blood in the urine), albuminuria, nephritis | |
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Target Organs
Eyes, skin, kidneys, liver, blood |
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| See also: INTRODUCTION See ICSC CARD: 0316 See MEDICAL TESTS: 0193 |