International Chemical Safety Cards FLUTOLANIL ICSC: 1265 alpha,alpha,alpha-Trifluoro-3'-isopropoxy-o-toluanilide N-(3-(1-Methylethoxy)phenyl)-2-(trifluoromethyl)benzamide C17H16F3NO2 Molecular mass: 323.3 ICSC #    1265 CAS #     66332-96-5 RTECS # CV5581320 April 20, 2004 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Liquid formulations containing organic solvents may be flammable. NO open flames. In case of fire in the surroundings: use appropriate extinguishing media. EXPLOSION EXPOSURE  •INHALATION Avoid inhalation of fine dust and mist. Fresh air, rest.  •SKIN Protective gloves. Rinse skin with plenty of water or shower.  •EYES Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Rest. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: P1 filter respirator for inert particles. Provision to contain effluent from fire extinguishing. R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 1265 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards FLUTOLANIL ICSC: 1265 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS TO WHITE CRYSTALS PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on burning producing toxic and corrosive fumes including hydrogen fluoride , nitrogen oxides , carbon monoxide . OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. ROUTES OF EXPOSURE: INHALATION RISK: Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. EFFECTS OF SHORT-TERM EXPOSURE: EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Melting point: 100-107°C Density: 1.3 g/cm3 Solubility in water, g/100 ml at 20°C: 0.001 (none) Vapour pressure, Pa at 20°C: negligible Octanol/water partition coefficient as log Pow: 3.7 ENVIRONMENTAL DATA The substance is toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use. N O T E S If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Health effects of exposure to the substance have been investigated extensively but none have been found. ADDITIONAL INFORMATION ICSC: 1265 FLUTOLANIL (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.