International Chemical Safety Cards para-CRESIDINE ICSC: 1180 2-Methoxy-5-methylaniline 5-Methyl-ortho-anisidine 3-Amino-para-cresol methyl ether 4-Methoxy-meta-toluidine 4-Methyl-2-aminoanisole C8H11NO / CH3OC6H3(CH3)NH2 Molecular mass: 137.2 ICSC #    1180 CAS #     120-71-8 RTECS # BZ6720000 EC #         612-209-00-X April 21, 2005 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION Finely dispersed particles form explosive mixtures in air. Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting. EXPOSURE See EFFECTS OF LONG-TERM OR REPEATED EXPOSURE. AVOID ALL CONTACT!  •INHALATION Cough. Local exhaust or breathing protection. Fresh air, rest.  •SKIN Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Safety spectacles or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Personal protection: P3 filter respirator for toxic particles. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Separated from strong oxidants, food and feedstuffs. Do not transport with food and feedstuffs. T symbol R: 45-22 S: 53-45 SEE IMPORTANT INFORMATION ON BACK ICSC: 1180 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards para-CRESIDINE ICSC: 1180 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: WHITE CRYSTALS. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating or producing toxic fumes and irritating fumes including nitrogen oxides . Reacts with strong oxidants. Attacks some forms of plastic, rubber and coatings. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK: Carcinogen category: 2; (DFG 2004). ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: This substance is possibly carcinogenic to humans. PHYSICAL PROPERTIES Boiling point: 235°C Melting point: 51.5°C Solubility in water: poor Vapour pressure, Pa at 25°C: 1.4 Flash point: 111°C Auto-ignition temperature: 450°C Octanol/water partition coefficient as log Pow: 1.67 ENVIRONMENTAL DATA N O T E S Do NOT take working clothes home. Depending on the degree of exposure, periodic medical examination is suggested. ADDITIONAL INFORMATION ICSC: 1180 para-CRESIDINE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.