International Chemical Safety Cards BENZONITRILE ICSC: 1103 Cyanobenzene Benzoic acid nitrile Phenyl cyanide C7H5N / C6H5(CN) Molecular mass: 103.1 ICSC #    1103 CAS #     100-47-0 RTECS # DI2450000 UN #        2224 EC #         608-012-00-3 October 19, 1999 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, AFFF, foam, carbon dioxide. EXPLOSION Above 75°C explosive vapour/air mixtures may be formed. Above 75°C use a closed system, ventilation. In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE PREVENT GENERATION OF MISTS!  •INHALATION Confusion. Headache. Laboured breathing. Nausea. Unconsciousness. Vomiting. Weakness. Ventilation, local exhaust, or breathing protection. Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.  •SKIN Redness. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.  •EYES Redness. Pain. Safety goggles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION (Further see Inhalation). Do not eat, drink, or smoke during work. Rinse mouth. Rest. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment. Chemical protection suit including self-contained breathing apparatus. Separated from food and feedstuffs . Well closed. Keep in a well-ventilated room. Do not transport with food and feedstuffs. Xn symbol R: 21/22 S: 2-23 UN Hazard Class: 6.1 UN Packing Group: II SEE IMPORTANT INFORMATION ON BACK ICSC: 1103 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards BENZONITRILE ICSC: 1103 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating or on burning, producing toxic fumes including hydrogen cyanide, nitrogen oxides. Reacts violently with strong acids to produce highly toxic hydrogen cyanide. Attacks some plastics. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the cellular respiration , resulting in cyanosis. The effects may be delayed. Medical observation is indicated. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 190.7°C Melting point: -12.8°C Relative density (water = 1): 1.0 Solubility in water: poor (0.1-0.5 g/100 ml at 22°C) Vapour pressure, Pa at 25°C: 102 Relative vapour density (air = 1): 3.6 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00 Flash point: 75°C c.c. Auto-ignition temperature: 550°C Explosive limits, vol% in air: 1.4-7.2 Octanol/water partition coefficient as log Pow: 1.56 ENVIRONMENTAL DATA The substance is harmful to aquatic organisms. N O T E S Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Transport Emergency Card: TEC (R)-61G61b ADDITIONAL INFORMATION ICSC: 1103 BENZONITRILE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.