International Chemical Safety Cards POTASSIUM THIOCYANATE ICSC: 1088 Thiocyanic acid, potassium salt Potassium sulfocyanate Potassium rhodanide KSCN Molecular mass: 97.18 ICSC #    1088 CAS #     333-20-0 RTECS # XL1925000 EC #         615-004-00-3 April 21, 2004 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. In case of fire in the surroundings: use appropriate extinguishing media. EXPLOSION EXPOSURE PREVENT DISPERSION OF DUST!  •INHALATION Cough. Further see Ingestion. Local exhaust or breathing protection. Fresh air, rest.  •SKIN Protective gloves. Remove contaminated clothes. Rinse skin with plenty of water or shower.  •EYES Safety goggles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Confusion. Convulsions. Nausea. Vomiting. Weakness. Do not eat, drink, or smoke during work. Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into covered containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder. Personal protection: P2 filter respirator for harmful particles. Separated from strong oxidants. Dry. Well closed. Note: A Xn symbol R: 20/21/22-32-52/53 S: 2-13-61 SEE IMPORTANT INFORMATION ON BACK ICSC: 1088 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards POTASSIUM THIOCYANATE ICSC: 1088 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS TO WHITE HYGROSCOPIC CRYSTALS PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating producing very toxic fumes: sulfur compounds,nitrogen oxidesandcyanides. Reacts violently with strong oxidants . On contact with water - strong cooling effect . OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and by ingestion. INHALATION RISK: A harmful concentration of airborne particles can be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The substance may cause effects on the central nervous system , resulting in excitement and convulsions. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the thyroid and central nervous system , resulting in impaired functions and hypothyroidism. PHYSICAL PROPERTIES Boiling point (decomposes): 500°C Melting point: 173°C Density: 1.9 g/cm3 Solubility in water: very good ENVIRONMENTAL DATA N O T E S NFPA Code: H3; F0; R0; ADDITIONAL INFORMATION ICSC: 1088 POTASSIUM THIOCYANATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.