International Chemical Safety Cards PHENOTHIAZINE ICSC: 0937 Dibenzothiazine Thiodiphenylamine C12H9NS Molecular mass: 199.3 ICSC #    0937 CAS #     92-84-2 RTECS # SN5075000 March 24, 1998 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION EXPOSURE PREVENT DISPERSION OF DUST! STRICT HYGIENE!  •INHALATION Cough. Sore throat. Ventilation (not if powder), local exhaust, or breathing protection. Fresh air, rest.  •SKIN Redness. Pain. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Pain. Face shield, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Abdominal pain. Nausea. Vomiting. Do not eat, drink, or smoke during work. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (Extra personal protection: P2 filter respirator for harmful particles). Separated from acids. Keep in the dark. R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 0937 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards PHENOTHIAZINE ICSC: 0937 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: YELLOW CRYSTALS. TURNS DEEP GREEN ON EXPOSURE TO LIGHT. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating, on contact with acids, producing toxic and irritating fumes including nitrogen oxides and sulfur oxides. OCCUPATIONAL EXPOSURE LIMITS: TLV: 5 mg/m3 (as TWA) (skin) (ACGIH 1996). OSHA PEL: none NIOSH REL: TWA 5 mg/m3 skin NIOSH IDLH: No data ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The substance irritates the eyes , the skin and the respiratory tract . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged contact may cause skin sensitization as well as photosensitization. PHYSICAL PROPERTIES Boiling point (decomposes): 371°C Melting point: 185.1°C Solubility in water: none Octanol/water partition coefficient as log Pow: 4.2 ENVIRONMENTAL DATA N O T E S Agrazine, Antiverm, Contaverm, Lethelmin, Nemazene, Padophene and Phenoverm are trade names. ADDITIONAL INFORMATION ICSC: 0937 PHENOTHIAZINE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.