International Chemical Safety Cards DIALLYLAMINE ICSC: 0866 Di-2-propenylamine N-2-Propenyl-2-propen-1-amine C6H11N / (CH2=CHCH2)2NH Molecular mass: 97.2 ICSC #    0866 CAS #     124-02-7 RTECS # UC6650000 UN #        2359 November 24, 1998 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames, NO sparks, and NO smoking. Powder, AFFF, foam, carbon dioxide. EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE PREVENT GENERATION OF MISTS! STRICT HYGIENE!  •INHALATION Cough. Shortness of breath. Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.  •SKIN Redness. Pain. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower.  •EYES Redness. Pain. Face shield, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Burning sensation. Cough. Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. (Extra personal protection: chemical protection suit including self-contained breathing apparatus). Fireproof. Separated from strong oxidants, strong acids, food and feedstuffs. Do not transport with food and feedstuffs. R: S: UN Hazard Class: 3 UN Subsidiary Risks: 6.1 and 8 UN Packing Group: II SEE IMPORTANT INFORMATION ON BACK ICSC: 0866 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards DIALLYLAMINE ICSC: 0866 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour mixes well with air, explosive mixtures are easily formed. CHEMICAL DANGERS: The substance decomposes on burning producing toxic fumes of nitrogen oxides. The solution in water is a medium strong base. Reacts violently with acids and oxidants. Attacks copper, tin, aluminium and zinc. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The vapour irritates the eyes, the skin and the respiratory tract. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 112°C Melting point: -88.4°C Relative density (water = 1): 0.76 Solubility in water, g/100 ml at 20°C: 9 Vapour pressure, kPa at 20°C: about 2.3 Relative vapour density (air = 1): 3.4 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.06 Flash point: 21°C Octanol/water partition coefficient as log Pow: 1.08 ENVIRONMENTAL DATA N O T E S Transport Emergency Card: TEC (R)-30G33 ADDITIONAL INFORMATION ICSC: 0866 DIALLYLAMINE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.