International Chemical Safety Cards 1-NAPHTHYLAMINE ICSC: 0518 alpha-Naphthylamine 1-Aminonaphthalene C10H9N Molecular mass: 143.2 ICSC #    0518 CAS #     134-32-7 RTECS # QM1400000 UN #        2077 EC #         612-020-00-2 October 04, 2000 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, alcohol-resistant foam, water spray, carbon dioxide. EXPLOSION EXPOSURE PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!  •INHALATION Blue lips or finger nails. Blue skin. Confusion. Dizziness. Headache. Shortness of breath. Weakness. Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.  •SKIN MAY BE ABSORBED! Redness. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Pain. Safety spectacles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Blue lips or fingernails. Blue skin. Dizziness. Headache. Nausea. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT wash away into sewer. Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. (Extra personal protection: P3 filter respirator for toxic particles). Dry. Keep in the dark. Well closed. Do not transport with food and feedstuffs. Xn symbol N symbol R: 22-51/53 S: 2-24-61 UN Hazard Class: 6.1 UN Packing Group: III SEE IMPORTANT INFORMATION ON BACK ICSC: 0518 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards 1-NAPHTHYLAMINE ICSC: 0518 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: WHITE CRYSTALS , WITH CHARACTERISTIC ODOUR. TURNS RED ON EXPOSURE TO AIR, LIGHT AND MOISTURE. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on burning producing nitrogen oxides and carbon monoxide . The substance is a weak base. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. OSHA PEL: 1910.1004 See Appendix B NIOSH REL: Ca See Appendix A NIOSH IDLH: Potential occupational carcinogen No data ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly. EFFECTS OF SHORT-TERM EXPOSURE: The substance is mildly irritating to the eyes and the skin. The substance may cause effects on the blood , resulting in the formation of methaemoglobin. The effects may be delayed. Medical observation is indicated. See Notes. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: See Notes. PHYSICAL PROPERTIES Boiling point: 300.8°C Melting point: 50.0°C Density: 1.12 g/cm3 Solubility in water: none Vapour pressure, Pa at 20°C: 0.53 Relative vapour density (air = 1): 4.93 Flash point: 157°C c.c. Auto-ignition temperature: 460°C Octanol/water partition coefficient as log Pow: 2.25 ENVIRONMENTAL DATA The substance is harmful to aquatic organisms. It is strongly advised not to let the chemical enter into the environment because it persists in the environment. N O T E S Depending on the degree of exposure, periodic medical examination is indicated. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Bladder cancers reported after occupational exposure to 1-naphthylamine may be due to contamination with 2-naphthylamine which is a human carcinogen. Transport Emergency Card: TEC (R)-61G12c NFPA Code: H2; F1; R0; ADDITIONAL INFORMATION ICSC: 0518 1-NAPHTHYLAMINE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.