International Chemical Safety Cards ZIRAM ICSC: 0348 Zinc dimethyldithiocarbamate bis(Dimethylcarbamodithioato-S,S')zinc ((CH3)2NCS•S)2Zn / C6H12N2S4Zn Molecular mass: 305.8 ICSC #    0348 CAS #     137-30-4 RTECS # ZH0525000 UN #        2771 EC #         006-012-00-2 October 02, 2000 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION Finely dispersed particles form explosive mixtures in air. Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting. In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE PREVENT DISPERSION OF DUST!  •INHALATION Abdominal pain. Cough. Nausea. Vomiting. Local exhaust or breathing protection. Fresh air, rest.  •SKIN Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION (Further see Inhalation). Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT wash away into sewer. Sweep spilled substance into plastic containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place . (Extra personal protection: P2 filter respirator for harmful particles). Do NOT let this chemical enter the environment. Separated from food and feedstuffs. Keep in a well-ventilated room. Well closed. Provision to contain effluent from fire extinguishing. Do not transport with food and feedstuffs. Marine pollutant. Xn symbol R: 22-36/37/38-40 S: 2-36/37 UN Hazard Class: 6.1 UN Packing Group: III SEE IMPORTANT INFORMATION ON BACK ICSC: 0348 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards ZIRAM ICSC: 0348 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: WHITE POWDER. PHYSICAL DANGERS: Dust explosion possible if in powder or granular form, mixed with air. CHEMICAL DANGERS: The substance decomposes on heating and on burning producing toxic and irritating fumes including nitrogen oxides and sulfur oxides . The substance decomposes on contact with acids . OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed . EFFECTS OF SHORT-TERM EXPOSURE: The substance irritates the eyes, the skin and the respiratory tract. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the central nervous system . PHYSICAL PROPERTIES Melting point: 240-250°C Relative density (water = 1): 1.7 Solubility in water: none Octanol/water partition coefficient as log Pow: 1.09 ENVIRONMENTAL DATA The substance is very toxic to aquatic organisms. N O T E S If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Transport Emergency Card: TEC (R)-61G12c ADDITIONAL INFORMATION ICSC: 0348 ZIRAM (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.