International Chemical Safety Cards METHYLDICHLOROSILANE ICSC: 0297 Dichloromethylsilane Monomethyldichlorosilane CH4Cl2Si / CH3SiHCl2 Molecular mass: 115.0 ICSC #    0297 CAS #     75-54-7 RTECS # VV3500000 UN #        1242 March 05, 2002 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames, NO sparks, and NO smoking. NO contact with hot surfaces. AFFF, powder, carbon dioxide. NO hydrous agents. NO water. EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. In case of fire: cool drums, etc., by spraying with water but avoid contact of the substance with water. EXPOSURE STRICT HYGIENE!  •INHALATION Burning sensation. Cough. Sore throat. Laboured breathing. Shortness of breath. Symptoms may be delayed (see Notes). Closed system and ventilation. Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. See Notes.  •SKIN Redness. Blisters. Pain. Skin burns. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.  •EYES Redness. Pain. Severe deep burns. Face shield, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Burning sensation. Abdominal pain. Shock or collapse. Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Give nothing to drink. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Evacuate danger area! Consult an expert! Collect leaking liquid in sealable dry containers ; do not use plastic containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. NEVER direct water jet on liquid. (Extra personal protection: complete protective clothing including self-contained breathing apparatus.) Fireproof. Separated from oxidants , food and feedstuffs , incompatible materials . See Chemical Dangers. Cool. Dry. Well closed. Keep under inert gas. Airtight. Unbreakable packaging; put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs. R: S: UN Hazard Class: 4.3 UN Subsidiary Risks: 3 and 8 UN Packing Group: I SEE IMPORTANT INFORMATION ON BACK ICSC: 0297 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards METHYLDICHLOROSILANE ICSC: 0297 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH PUNGENT ODOUR. PHYSICAL DANGERS: The vapour is heavier than air and may travel along the ground; distant ignition possible. CHEMICAL DANGERS: On contact with hot surfaces or flames this substance decomposes forming toxic and corrosive fumes including hydrogen chloride andphosgene. The substance decomposes on contact with bases , forming flammable/explosive gas (hydrogen - see ICSC0001) . Reacts violently with oxidants. Reacts violently with water to produce hydrogen chloride (see ICSC 0163) . Reacts in the presence of potassium permanganate, lead(II) oxide, copper oxide or silver oxide , causing fire and explosion hazard. Attacks many metals in presence of water. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour and by ingestion . INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is corrosive to the eyes, the skin and the respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema (see Notes). Exposure may result in death. Medical observation is indicated. See Notes. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 41°C Melting point: -92°C Relative density (water = 1): 1.1 Solubility in water: reaction Vapour pressure, kPa at 20°C: 47.1 Relative vapour density (air = 1): 3.97 Relative density of the vapour/air-mixture at 20°C (air = 1): 2.38 Flash point: -22°C c.c. Auto-ignition temperature: 290°C Explosive limits, vol% in air: 2.4-55 ENVIRONMENTAL DATA N O T E S Reacts violently with fire extinguishing agents such as water. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered. Transport Emergency Card: TEC (R)-43S1242 NFPA Code: H3; F3; R2; W ADDITIONAL INFORMATION ICSC: 0297 METHYLDICHLOROSILANE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.