International Chemical Safety Cards TRI-ALLATE ICSC: 0201 S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate C10H16Cl3NOS / ((CH3)2CH)2NCOSCH2CCl=CCl2 Molecular mass: 304.7 ICSC #    0201 CAS #     2303-17-5 RTECS # EZ8575000 EC #         006-039-00-X April 21, 2005 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. In case of fire in the surroundings: use appropriate extinguishing media. EXPLOSION EXPOSURE  •INHALATION Avoid inhalation of fine dust and mist. Fresh air, rest.  •SKIN Redness. Protective gloves. Remove contaminated clothes. Rinse skin with plenty of water or shower.  •EYES Redness. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Personal protection: A/P2 filter respirator for organic vapour and harmful dust. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment. Separated from food and feedstuffs. Do not transport with food and feedstuffs. Xn symbol N symbol R: 22-43-48/22-50/53 S: (2)-24-37-60-61 SEE IMPORTANT INFORMATION ON BACK ICSC: 0201 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards TRI-ALLATE ICSC: 0201 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: CLEAR LIQUID OR COLOURLESS CRYSTALS PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating above 200°C producing toxic and corrosive gases including hydrogen chloridenitrogen oxides and sulfur oxides. Attacks many metals. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and by ingestion. INHALATION RISK: A harmful concentration of airborne particles can be reached quickly on spraying or when dispersed, especially if powdered. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyesandthe skin. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point at 0.04 kPa: 117°C Melting point: 29-30°C Relative density (water = 1): 1.27 Solubility in water, g/100 ml at 25°C: 0.0002 Vapour pressure, Pa at 25°C: 0.016 Relative vapour density (air = 1): 10.5 Flash point: 90°C c.c. Octanol/water partition coefficient as log Pow: 3.98 (calculated) ENVIRONMENTAL DATA The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal. N O T E S Technical Tri-allate is an oily amber liquid. If the substance is formulated with solvents also consult the ICSCs of these materials. Carrier solvents used in commercial formulations may change physical and toxicological properties. Avadex BW, Dipthal and Far-Go are trade names. ADDITIONAL INFORMATION ICSC: 0201 TRI-ALLATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.