International Chemical Safety Cards VINYLIDENE CHLORIDE ICSC: 0083 1,1-Dichloroethene 1,1-Dichloroethylene VDC C2H2Cl2 / H2C=CCl2 Molecular mass: 97 ICSC #    0083 CAS #     75-35-4 RTECS # KV9275000 UN #        1303 (stabilized) EC #         602-025-00-8 April 13, 2000 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Extremely flammable. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames, NO sparks, and NO smoking. Powder, water spray, foam, carbon dioxide. EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, explosion-proof electrical equipment and lighting. Use non-sparking handtools. In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE PREVENT GENERATION OF MISTS!  •INHALATION Dizziness. Drowsiness. Unconsciousness. Ventilation, local exhaust, or breathing protection. Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.  •SKIN Redness. Pain. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Pain. Safety goggles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Abdominal pain. Sore throat. (Further see Inhalation). Do not eat, drink, or smoke during work. Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Rest. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Evacuate danger area! Consult an expert! Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Personal protection: complete protective clothing including self-contained breathing apparatus. Fireproof. Provision to contain effluent from fire extinguishing. Separated from incompatible materials (see Chemical Dangers). Cool. Keep in the dark. Store only if stabilized. Airtight. Unbreakable packaging; put breakable packaging into closed unbreakable container. Marine pollutant. Note: D F+ symbol Xn symbol R: 12-20-40 S: 2-7-16-29-36/37-46 UN Hazard Class: 3 UN Packing Group: I SEE IMPORTANT INFORMATION ON BACK ICSC: 0083 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards VINYLIDENE CHLORIDE ICSC: 0083 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: VOLATILE COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour is heavier than air and may travel along the ground; distant ignition possible. Vinylidine chloride monomer vapours are uninhibited and may form polymers in vents or flame arresters of storage tanks, resulting in blockage of vents. CHEMICAL DANGERS: The substance can readily form explosive peroxides. The substance willl polymerize readily due to heating or under the influence of oxygen, sunlight, copper or aluminium, with fire or explosion hazard. May explode on heating or on contact with flames. The substance decomposes on burning producing toxic and corrosive fumes ( hydrogen chloride , phosgene ). Reacts violently with oxidants. OCCUPATIONAL EXPOSURE LIMITS: TLV: 5 ppm as TWA; A4 (not classifiable as a human carcinogen); (ACGIH 2004). MAK: 2 ppm, 8.0 mg/m³; Peak limitation category: II(2); Carcinogen category: 3B; Pregnancy risk group: C; (DFG 2004). OSHA PEL: none NIOSH REL: Ca See Appendix A NIOSH IDLH: Potential occupational carcinogen No data ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation and by ingestion. INHALATION RISK: A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance irritates the eyes, the skin and the respiratory tract. Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis. Exposure at high levels could cause lowering of consciousness. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the kidneys and liver . PHYSICAL PROPERTIES Boiling point: 32°C Melting point: -122°C Relative density (water = 1): 1.2 Solubility in water, g/100 ml at 25°C: 0.25 Vapour pressure, kPa at 20°C: 66.5 Relative vapour density (air = 1): 3.3 Relative density of the vapour/air-mixture at 20°C (air = 1): 2.5 Flash point: -25°C c.c. Auto-ignition temperature: 570°C Explosive limits, vol% in air: 5.6-16 Octanol/water partition coefficient as log Pow: 1.32 ENVIRONMENTAL DATA The substance is harmful to aquatic organisms. N O T E S Depending on the degree of exposure, periodic medical examination is suggested. An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. The odour warning when the exposure limit value is exceeded is insufficient. Do NOT use in the vicinity of a fire or a hot surface, or during welding. Card has been partly updated October 2004 and in April 2005. See section Occupational Exposure Limits. Transport Emergency Card: TEC (R)-30S1303 NFPA Code: H2; F4; R2; ADDITIONAL INFORMATION ICSC: 0083 VINYLIDENE CHLORIDE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.