NIOSH Pocket Guide to Chemical Hazards

Thiram

CAS 137-26-8

C6H12N2S4

RTECS JO1400000
Synonyms & Trade Names
bis(Dimethylthiocarbamoyl) disulfide, Tetramethylthiuram disulfide
DOT ID & Guide
2771 151

Exposure
Limits

NIOSH REL: TWA 5 mg/m3
OSHA PEL: TWA 5 mg/m3
IDLH 100 mg/m3 See: 137268 Conversion
Physical Description
Colorless to yellow, crystalline solid with a characteristic odor. [Note: Commercial pesticide products may be dyed blue.]
MW: 240.4
BP: Decomposes
MLT: 312°F
Sol: 0.003%
VP: 0.000008 mmHg
IP: ?

Sp.Gr: 1.29
Fl.P: ?
UEL: ?
LEL: ?

Combustible Solid
Incompatibilities & Reactivities
Strong oxidizers, strong acids, oxidizable materials
Measurement Methods
NIOSH 5005
See: NMAM or OSHA Methods
Personal Protection & Sanitation (See protection)
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: Daily

First Aid (See procedures)
Eye: Irrigate immediately
Skin: Soap wash promptly
Breathing: Respiratory support
Swallow: Medical attention immediately
Important additional information about respirator selection
Respirator Recommendations NIOSH/OSHA
Up to 50 mg/m3:
(APF = 10) Any air-purifying half-mask respirator with organic vapor cartridge(s) in combination with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100, P100. Click here for information on selection of N, R, or P filters.*
(APF = 10) Any supplied-air respirator*
Up to 100 mg/m3:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode*
(APF = 50) Any air-purifying full-facepiece respirator equipped with organic vapor cartridge(s) in combination with an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters.
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters.
(APF = 25) Any powered air-purifying respirator with an organic vapor cartridge in combination with a high-efficiency particulate filter.*
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter. Click here for information on selection of N, R, or P filters./Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, ingestion, skin and/or eye contact
Symptoms Irritation eyes, skin, mucous membrane; dermatitis; Antabuse-like effects
Target Organs Eyes, skin, respiratory system, central nervous system
See also: INTRODUCTION   See ICSC CARD: 0757