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Sulfur monochloride |
CAS 10025-67-9 | ||
S2Cl2 |
RTECS WS4300000 | ||
Synonyms & Trade Names Sulfur chloride, Sulfur subchloride, Thiosulfurous dichloride |
DOT ID & Guide 1828 137 |
Exposure
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NIOSH REL: C 1 ppm (6 mg/m3) | ||
OSHA PEL†: TWA 1 ppm (6 mg/m3) | |||
IDLH 5 ppm See: 10025679 | Conversion 1 ppm = 5.52 mg/m3 |
Physical Description Light-amber to yellow-red, oily liquid with a pungent, nauseating, irritating odor. |
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MW: 135.0 |
BP: 280°F |
FRZ: -107°F |
Sol: Decomposes |
VP: 7 mmHg |
IP: 9.40 eV |
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Sp.Gr: 1.68 |
Fl.P: 245°F |
UEL: ? |
LEL: ? |
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Class IIIB Combustible Liquid: Fl.P. at or above 200°F. | |||
Incompatibilities & Reactivities Peroxides, oxides of phosphorous, organics, water [Note: Decomposes violently in water to form hydrochloric acid, sulfur dioxide, sulfur, sulfite, thiosulfate, and hydrogen sulfide. Corrosive to metals.] |
Measurement Methods None available See: NMAM or OSHA Methods |
Personal Protection & Sanitation (See protection) Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: No recommendation Provide: Eyewash, Quick drench |
First Aid (See procedures) Eye: Irrigate immediately Skin: Water flush immediately Breathing: Respiratory support Swallow: Medical attention immediately |
Important additional information about respirator selection Respirator Recommendations NIOSH/OSHA Up to 5 ppm: (APF = 50) Any chemical cartridge respirator with a full facepiece and cartridge(s) providing protection against the compound of concern (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern (APF = 25) Any powered, air-purifying respirator with cartridge(s) providing protection against the compound of concern£ (APF = 50) Any self-contained breathing apparatus with a full facepiece (APF = 50) Any supplied-air respirator with a full facepiece Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode (APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern/Any appropriate escape-type, self-contained breathing apparatus |
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Exposure Routes inhalation, ingestion, skin and/or eye contact | |
Symptoms Irritation eyes, skin, mucous membrane; lacrimation (discharge of tears); cough; eye, skin burns; pulmonary edema | |
Target Organs
Eyes, skin, respiratory system |
See also: INTRODUCTION See ICSC CARD: 0958 See MEDICAL TESTS: 0216 |