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Chlorine dioxide |
CAS 10049-04-4 | ||
ClO2 |
RTECS FO3000000 | ||
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Synonyms & Trade Names Chlorine oxide, Chlorine peroxide |
DOT ID & Guide 9191 143 (hydrate, frozen) |
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Exposure
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NIOSH REL: TWA 0.1 ppm (0.3 mg/m3) ST 0.3 ppm (0.9 mg/m3) | ||
| OSHA PEL†: TWA 0.1 ppm (0.3 mg/m3) | |||
| IDLH 5 ppm See: 10049044 | Conversion 1 ppm = 2.76 mg/m3 | ||
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Physical Description Yellow to red gas or a red-brown liquid (below 52°F) with an unpleasant odor similar to chlorine and nitric acid. |
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MW: 67.5 |
BP: 52°F |
FRZ: -74°F |
Sol(77°F): 0.3% |
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VP: >1 atm |
IP: 10.36 eV |
RGasD: 2.33 |
Sp.Gr: 1.6 (Liquid at 32°F) |
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Fl.P: NA (Gas) ? (Liquid) |
UEL: ? |
LEL: ? |
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| Flammable Gas/Combustible Liquid | |||
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Incompatibilities & Reactivities Organic materials, heat, phosphorus, potassium hydroxide, sulfur, mercury, carbon monoxide [Note: Unstable in light. A powerful oxidizer.] |
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Measurement Methods OSHA ID126SGX, ID202 See: NMAM or OSHA Methods |
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Personal Protection & Sanitation (See protection) Skin: Prevent skin contact (liquid) Eyes: Prevent eye contact (liquid) Wash skin: When contaminated (liquid) Remove: When wet (flammable) Change: No recommendation Provide: Eyewash (liquid), Quick drench (liquid) |
First Aid (See procedures) Eye: Irrigate immediately (liquid) Skin: Soap wash immediately (liquid) Breathing: Respiratory support Swallow: Medical attention immediately (liquid) |
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Important additional information about respirator selection Respirator Recommendations NIOSH/OSHA Up to 1 ppm: (APF = 10) Any chemical cartridge respirator with cartridge(s) providing protection against the compound of concern (APF = 10) Any supplied-air respirator Up to 2.5 ppm: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode£ (APF = 25) Any powered, air-purifying respirator with cartridge(s) providing protection against the compound of concern£ Up to 5 ppm: (APF = 50) Any chemical cartridge respirator with a full facepiece and cartridge(s) providing protection against the compound of concern (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern (APF = 50) Any self-contained breathing apparatus with a full facepiece (APF = 50) Any supplied-air respirator with a full facepiece Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure- demand or other positive-pressure mode (APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern¿/Any appropriate escape-type, self-contained breathing apparatus |
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| Exposure Routes inhalation, ingestion (liquid), skin and/or eye contact | |
| Symptoms Irritation eyes, nose, throat; cough, wheezing, bronchitis, pulmonary edema; chronic bronchitis | |
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Target Organs
Eyes, respiratory system |
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| See also: INTRODUCTION See ICSC CARD: 0127 See MEDICAL TESTS: 0045 |