International Chemical Safety Cards CARBENDAZIM ICSC: 1277 Methyl benzimidazole-2-ylcarbamate Methyl (1H-benzimidazol-2-yl)carbamate Carbendazol 1H-Benzimidazol-2-ylcarbamic acid methyl ester C9H9N3O2 Molecular mass: 191.2 ICSC #    1277 CAS #     10605-21-7 RTECS # DD6500000 EC #         613-048-00-8 March 25, 1998 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Gives off irritating or toxic fumes (or gases) in a fire. Water spray, powder. EXPLOSION EXPOSURE PREVENT DISPERSION OF DUST! AVOID EXPOSURE OF (PREGNANT) WOMEN! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!  •INHALATION Avoid inhalation of fine dust and mist. Fresh air, rest.  •SKIN Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Rest. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Separated from bases , food and feedstuffs . T symbol N symbol R: 46-60-61-50/53 S: 53-45-60-61 SEE IMPORTANT INFORMATION ON BACK ICSC: 1277 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards CARBENDAZIM ICSC: 1277 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS CRYSTALS OR GREY TO WHITE POWDER. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes slowly on contact with bases . OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered. EFFECTS OF SHORT-TERM EXPOSURE: EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Animal tests show that this substance possibly causes toxicity to human reproduction or development. PHYSICAL PROPERTIES Melting point (decomposes): 302-307°C Density: 0.27 g/cm3 Solubility in water, g/100 ml at 24°C: 0.0008 Vapour pressure, Pa at 20°C: negligible Octanol/water partition coefficient as log Pow: 1.49 ENVIRONMENTAL DATA The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use. N O T E S If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Aimcozim, BAS 3460F, Battal, Bavistin, Bendazim, Carbate, Carbendor, Cekudazim, Corbel, Custos, Defensor, Delsene, Derosal, Derroprene, Equitdazin, Hoe17411, Kemdazin, Lignasan, Pillarstin, Stempor, Supercarb,Triticol are trade names. Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response. ADDITIONAL INFORMATION ICSC: 1277 CARBENDAZIM (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.