International Chemical Safety Cards TRIFLUMIZOLE ICSC: 1252 (E)-4-Chloro-alpha,alpha,alpha-trifluoro-N-(1-imidazol-1-yl)-2-propoxyethylidene-o-toluidine 1-(1((4-Chloro-2-(trifluoromethyl)phenyl)imino)-2-propoxyethyl)-1H-imidazole C15H15ClF3N3O Molecular mass: 345.7 ICSC #    1252 CAS #     68694-11-1 RTECS # NI4490000 March 13, 1995 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. In case of fire in the surroundings: all extinguishing agents allowed. EXPLOSION Risk of fire and explosion if formulations contain flammable/explosive solvents. EXPOSURE STRICT HYGIENE!  •INHALATION Ventilation. Fresh air, rest. Refer for medical attention.  •SKIN Protective gloves. Protective clothing. Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.  •EYES Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Do NOT wash away into sewer. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (extra personal protection: P2 filter respirator for harmful particles). Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room. Do not transport with food and feedstuffs. R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 1252 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards TRIFLUMIZOLE ICSC: 1252 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS CRYSTALS. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on burning producing toxic and corrosive fumes including nitrogen oxides, hydrogen fluoride, and hydrogen chloride (see ICSC 0283 and ICSC 0163). OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation or by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the liver, blood , resulting in liver impairment, decrease in hemoglobin. PHYSICAL PROPERTIES Melting point: 63°C Relative density (water = 1): 1.4 Solubility in water, g/100 ml at 20°C: 1.25 (moderate) Vapour pressure, Pa at 25°C: 0.0014 Octanol/water partition coefficient as log Pow: 1.4 ENVIRONMENTAL DATA The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use. N O T E S Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. The relation between odour and the occupational exposure limit cannot be indicated. Condor, Duo Top, Procure, Terraguard, Trifmine are trade names. ADDITIONAL INFORMATION ICSC: 1252 TRIFLUMIZOLE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.