International Chemical Safety Cards TRISODIUM PHOSPHATE (ANHYDROUS) ICSC: 1178 Sodium phosphate, tribasic Trisodium orthophosphate Na3PO4 Molecular mass: 163.9 ICSC #    1178 CAS #     7601-54-9 RTECS # TC9490000 October 23, 1995 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. In case of fire in the surroundings: all extinguishing agents allowed. EXPLOSION EXPOSURE AVOID ALL CONTACT!  •INHALATION Burning sensation. Cough. Shortness of breath. Sore throat. Local exhaust or breathing protection. Fresh air, rest. Half-upright position. Refer for medical attention.  •SKIN Skin burns. Pain. Blisters. Protective clothing. Rinse with plenty of water, do NOT remove clothes. Refer for medical attention.  •EYES Redness. Pain. Severe deep burns. Face shield or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Abdominal pain. Burning sensation. Shock or collapse. Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Rest. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place (extra personal protection: complete protective clothing including self-contained breathing apparatus). Separated from strong acids. Dry. Well closed. R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 1178 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards TRISODIUM PHOSPHATE (ANHYDROUS) ICSC: 1178 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS TO WHITE CRYSTALS. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating producing toxic and corrosive fumes including phosphorous oxides. The solution in water is a strong base, it reacts violently with acid and is corrosive. Attacks many metals in presence of water. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The substance is corrosive to the eyes, the skin and the respiratory tract. Corrosive on ingestion. Inhalation of dust may cause lung oedema (see Notes). EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Melting point (decomposes): 75°C Relative density (water = 1): 2.5 Solubility in water, g/100 ml: 8.8 ENVIRONMENTAL DATA N O T E S The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered. ADDITIONAL INFORMATION ICSC: 1178 TRISODIUM PHOSPHATE (ANHYDROUS) (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.