International Chemical Safety Cards METHYL PROPIONATE ICSC: 1029 Propanoic acid, methyl ester C4H8O2 / C2H5COOCH3 Molecular mass: 88.1 ICSC #    1029 CAS #     554-12-1 RTECS # UF5970000 UN #        1248 EC #         607-027-00-2 October 28, 2004 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Highly flammable. Gives off irritating gases and toxic fumes in a fire. NO open flames, NO sparks, and NO smoking. NO contact with oxidants. Powder, alcohol-resistant foam, water spray, carbon dioxide. EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Use non-sparking handtools. In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE  •INHALATION Cough. Sore throat. Ventilation, local exhaust, or breathing protection. Fresh air, rest.  •SKIN Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Pain. Safety goggles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Abdominal pain. Vomiting. Do not eat, drink, or smoke during work. Rinse mouth. Give plenty of water to drink. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Remove all ignition sources. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. Personal protection: filter respirator for organic gases and vapours. Fireproof. Cool. Separated from oxidants . F symbol Xn symbol R: 11-20 S: 2-16-24-29-33 UN Hazard Class: 3 UN Packing Group: II SEE IMPORTANT INFORMATION ON BACK ICSC: 1029 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards METHYL PROPIONATE ICSC: 1029 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour is heavier than air and may travel along the ground; distant ignition possible. As a result of flow, agitation, etc., electrostatic charges can be generated. CHEMICAL DANGERS: The substance decomposes on heating producing irritating fumes. Reacts with oxidants causing fire hazard. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. ROUTES OF EXPOSURE: INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the respiratory tract , the skin and the eyes . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point: 80°C Melting point: -88°C Relative density (water = 1): 0.92 Solubility in water, g/100 ml at 25°C: 6.2 Vapour pressure, kPa at 20°C: 8.5 Relative vapour density (air = 1): 3 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.2 Flash point: -2°C c.c. Auto-ignition temperature: 469°C Explosive limits, vol% in air: 2.5-13.0 Octanol/water partition coefficient as log Pow: 0.82 ENVIRONMENTAL DATA N O T E S Environmental effects from the substance have not been investigated adequately. This substance is used as a strawberry flavour in food. Transport Emergency Card: TEC (R)-30S1248 NFPA Code: H1; F3; R0 ADDITIONAL INFORMATION ICSC: 1029 METHYL PROPIONATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.