International Chemical Safety Cards NITROFEN ICSC: 0929 2,4-Dichloro-1-(4-nitrophenoxy) benzene 2,4-Dichlorophenyl p-nitrophenyl ether C12H7Cl2NO3 / C6H3Cl2OC6H4NO2 Molecular mass: 284.1 ICSC #    0929 CAS #     1836-75-5 RTECS # KN8400000 EC #         609-040-00-9 March 24, 1999 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Powder, water spray, foam, carbon dioxide. EXPLOSION Finely dispersed particles form explosive mixtures in air. Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting. EXPOSURE PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! AVOID EXPOSURE OF (PREGNANT) WOMEN! IN ALL CASES CONSULT A DOCTOR!  •INHALATION Abdominal pain. Cough. Diarrhoea. Dizziness. Headache. Laboured breathing. Sore throat. Vomiting. Local exhaust or breathing protection. Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.  •SKIN Redness. Pain. Protective gloves. Protective clothing. First rinse with plenty of water, then remove contaminated clothes and rinse again. Refer for medical attention.  •EYES Redness. Pain. Safety spectacles, or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION (See Inhalation). Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Rest. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. (Extra personal protection: P3 filter respirator for toxic particles). Separated from food and feedstuffs. Well closed. Do not transport with food and feedstuffs. Note: E T symbol N symbol R: 45-61-22-50/53 S: 53-45-60-61 SEE IMPORTANT INFORMATION ON BACK ICSC: 0929 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards NITROFEN ICSC: 0929 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: COLOURLESS TO BROWN CRYSTALLINE POWDER, TURNS DARK ON EXPOSURE TO LIGHT. PHYSICAL DANGERS: Dust explosion possible if in powder or granular form, mixed with air. CHEMICAL DANGERS: On combustion, forms toxic fumes. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or dispersing. EFFECTS OF SHORT-TERM EXPOSURE: The substance irritates the skin and the respiratory tract. The substance may cause effects on the central nervous system. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the liver. This substance is possibly carcinogenic to humans. Animal tests show that this substance possibly causes malformations in human babies. PHYSICAL PROPERTIES Boiling point at 101.3 kPa: 368°C Melting point: 70-71°C Density: 1.3 g/cm3 Solubility in water, g/100 ml at 22°C: 0.0001 Vapour pressure, Pa at 40°C: 0.001 Flash point: >200°C c.c. Auto-ignition temperature: >400°C Octanol/water partition coefficient as log Pow: 3.4-5 ENVIRONMENTAL DATA The substance is very toxic to aquatic organisms. In the food chain important to humans, bioaccumulation takes place, specifically in fish. The substance may cause long-term effects in the aquatic environment. Avoid release to the environment in circumstances different to normal use. N O T E S If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. Tok-2, Tok E25, Tokkorn, Mezotox, FW925, Niclofen, NIP, Nitrochlor, Trazalex are trade names. ADDITIONAL INFORMATION ICSC: 0929 NITROFEN (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.