International Chemical Safety Cards DIETHYLENE BENZYL BENZOATE ICSC: 0447 2,2'-Oxybisethanol dibenzoate Diethylene glycol dibenzoate (C6H5COOCH2CH2)2O Molecular mass: 314.4 ICSC #    0447 CAS #     120-55-8 RTECS # ID6650000 April 08, 1997 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Water spray, alcohol-resistant foam, powder, carbon dioxide, (see Notes). EXPLOSION EXPOSURE PREVENT DISPERSION OF DUST!  •INHALATION Fresh air, rest.  •SKIN Redness. Protective gloves. Rinse skin with plenty of water or shower.  •EYES Redness. Safety spectacles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Ventilation along the floor. R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 0447 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards DIETHYLENE BENZYL BENZOATE ICSC: 0447 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: CRYSTALS. PHYSICAL DANGERS: The vapour is heavier than air. CHEMICAL DANGERS: On combustion, forms irritating fumes. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation. INHALATION RISK: Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly. EFFECTS OF SHORT-TERM EXPOSURE: The substance is mildly irritating to the eyes and the skin . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point at 0.7 kPa: 236°C Melting point: 28°C Relative density (water = 1): 1.2 Solubility in water, g/100 ml: miscible Relative vapour density (air = 1): 9.4 Flash point: 232°C ENVIRONMENTAL DATA N O T E S Use of alcohol foam, foam and water as extinguishing agent may cause frothing. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. NFPA Code: H0; F1; R0; ADDITIONAL INFORMATION ICSC: 0447 DIETHYLENE BENZYL BENZOATE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.