International Chemical Safety Cards ALLETHRIN ICSC: 0212 (RS)-3-Allyl-2-methyl-4-oxocyclopent-2-enyl (1RS)-cis-trans-chrysanthemate 2-Methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate C19H26O3 Molecular mass: 302.4 ICSC #    0212 CAS #     584-79-2 RTECS # GZ1476000 UN #        3352 EC #         006-025-00-3 March 12, 2001 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. Liquid formulations containing organic solvents may be flammable. NO open flames. Powder, AFFF, foam, carbon dioxide. EXPLOSION In case of fire: keep drums, etc., cool by spraying with water. EXPOSURE PREVENT GENERATION OF MISTS!  •INHALATION Cough. Ventilation, local exhaust, or breathing protection. Fresh air, rest.  •SKIN Redness. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.  •EYES Redness. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. (Extra personal protection: A/P2 filter respirator for organic vapour and harmful dust.) Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . Keep in a well-ventilated room. Do not transport with food and feedstuffs. Note: C Xn symbol N symbol R: 20/22-50/53 S: 2-36-60-61 UN Hazard Class: 6.1 UN Packing Group: III SEE IMPORTANT INFORMATION ON BACK ICSC: 0212 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards ALLETHRIN ICSC: 0212 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: PALE YELLOW VISCOUS LIQUID. PHYSICAL DANGERS: CHEMICAL DANGERS: The substance decomposes on heating above 400°C producing irritating fumes . OCCUPATIONAL EXPOSURE LIMITS: TLV not established. ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes , the skin and the respiratory tract . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: PHYSICAL PROPERTIES Boiling point at 0.013 kPa: 140°C Melting point: about 4°C Relative density (water = 1): 1.01 Solubility in water: none Vapour pressure, Pa at 20°C: <10 Octanol/water partition coefficient as log Pow: 4.78 ENVIRONMENTAL DATA The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use. N O T E S Carrier solvents used in commercial formulations may change physical and toxicological properties. Pynamin, Pyresin are trade names. Also consult publication Health and Safety Guide No. 24 Allethrins, and Environmental Health Criteria No. 87 Allethrins, of IPCS. Also consult ICSC 0228 (S-Bioallethrin), 0213 (d-Allethrin), 0227 (Bioallethrin). Transport Emergency Card: TEC (R)-61G43c ADDITIONAL INFORMATION ICSC: 0212 ALLETHRIN (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.