International Chemical Safety Cards MANGANESE ICSC: 0174 Mn Atomic mass: 54.9 (powder) ICSC #    0174 CAS #     7439-96-5 RTECS # OO9275000 November 27, 2003 Peer reviewed TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/ SYMPTOMS PREVENTION FIRST AID/ FIRE FIGHTING FIRE Combustible. NO open flames. Dry sand, special powder. EXPLOSION Finely dispersed particles form explosive mixtures in air. Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting. EXPOSURE PREVENT DISPERSION OF DUST! AVOID EXPOSURE OF (PREGNANT) WOMEN!  •INHALATION Cough. Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.  •SKIN Protective gloves. Rinse and then wash skin with water and soap.  •EYES Safety goggles, or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.  •INGESTION Abdominal pain. Nausea. Do not eat, drink, or smoke during work. Rinse mouth. Refer for medical attention. SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING Sweep spilled substance into containers. Carefully collect remainder, then remove to safe place. (Extra personal protection: P2 filter respirator for harmful particles.) Separated from acids. Dry. R: S: SEE IMPORTANT INFORMATION ON BACK ICSC: 0174 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards MANGANESE ICSC: 0174 I M P O R T A N T D A T A PHYSICAL STATE; APPEARANCE: GREY - WHITE POWDER PHYSICAL DANGERS: Dust explosion possible if in powder or granular form, mixed with air. CHEMICAL DANGERS: Reacts slowly with water more rapidly with steam and acids forming flammable/explosive gas (hydrogen - see ICSC0001) causing fire and explosion hazard. OCCUPATIONAL EXPOSURE LIMITS: TLV: 0.2 mg/m³ (as TWA); Intended change; (ACGIH 2003). MAK: 0.5 I mg/m³; Pregnancy risk group: C; (DFG 2003). ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The aerosol is irritating to the respiratory tract . EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the lungs and central nervous system , resulting in increased susceptibility to bronchitis, pneumonitis and neurologic, neuropsychiatric disorders (manganism). Animal tests show that this substance possibly causes toxicity to human reproduction or development. PHYSICAL PROPERTIES Boiling point: 1962°C Melting point: 1244°C Density: 7.47 g/cm3 Solubility in water: none ENVIRONMENTAL DATA This substance may be hazardous in the environment; special attention should be given to aquatic organisms. N O T E S Depending on the degree of exposure, periodic medical examination is suggested. The recommendations on this Card also apply to ferro manganese. ADDITIONAL INFORMATION ICSC: 0174 MANGANESE (C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.