International Chemical Safety Cards

CUMENE

ICSC: 0170

(1-Methylethyl)benzene
2-Phenylpropane
Isopropylbenzene
C₉H₁₂ / C₆H₅CH(CH₃)₂
Molecular mass: 120.2

ICSC #    0170
CAS #     98-82-8
RTECS # GR8575000
UN #        1918
EC #         601-024-00-X
April 13, 2000 Peer reviewed

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Flammable.	NO open flames, NO sparks, and NO smoking.	Powder, AFFF, foam, carbon dioxide.
EXPLOSION	Above 31°C explosive vapour/air mixtures may be formed.	Above 31°C use a closed system, ventilation, and explosion-proof electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).	In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE		PREVENT GENERATION OF MISTS!
•INHALATION	Dizziness. Ataxia. Drowsiness. Headache. Unconsciousness.	Ventilation, local exhaust, or breathing protection.	Fresh air, rest. Refer for medical attention.
•SKIN	Dry skin.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
•EYES	Redness. Pain.	Safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION	(See Inhalation).	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment. Personal protection: filter respirator for organic gases and vapours.

Fireproof. Separated from strong oxidants, acids. Cool. Keep in the dark. Store only if stabilized.

Marine pollutant.
Note: C
Xn symbol
N symbol
R: 10-37-51/53-65
S: 2-24-37-61-62
UN Hazard Class: 3
UN Packing Group: III

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0170

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

CUMENE

ICSC: 0170

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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:
As a result of flow, agitation, etc., electrostatic charges can be generated.

CHEMICAL DANGERS:
Reacts violently with acids and strong oxidants causing fire and explosion hazard. The substance can form explosive peroxides.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 50 ppm as TWA; (ACGIH 2004).
MAK: 50 ppm, 250 mg/mł;
Peak limitation category: II(4);
skin absorption (H);
Pregnancy risk group: C;
(DFG 2004).
OSHA PEL: TWA 50 ppm (245 mg/m³) skin
NIOSH REL: TWA 50 ppm (245 mg/m³) skin
NIOSH IDLH: 900 ppm LEL

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and through the skin.

INHALATION RISK:
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes and the skin . Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis. The substance may cause effects on the central nervous system . Exposure far above the OEL may result in unconsciousness.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis.

PHYSICAL
PROPERTIES

Boiling point: 152°C
Melting point: -96°C
Relative density (water = 1): 0.90
Solubility in water:
none
Vapour pressure, Pa at 20°C: 427
Relative vapour density (air = 1): 4.2

Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
Flash point:
31°C c.c.
Auto-ignition temperature: 420°C
Explosive limits, vol% in air: 0.9-6.5
Octanol/water partition coefficient as log Pow: 3.66

ENVIRONMENTAL
DATA

The substance is toxic to aquatic organisms.

N O T E S

Check for peroxides prior to distillation; eliminate if found. Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response.

Transport Emergency Card: TEC (R)-30S1918 or 30GF1-III
NFPA Code: H2; F3; R1

ADDITIONAL INFORMATION

ICSC: 0170	CUMENE
(C) IPCS, CEC, 1994

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.